Soluble species in aerosol and snow and their relationship at Glacier 1, Tien Shan, China

Simultaneous sampling of aerosol (n = 20) and snow (n = 114) was made at Glacier 1, Tien Shan, between May 19 and June 29, 1996. Similar temporal patterns of some major ion (calcium, magnesium, potassium, sodium, chloride, and sulfate) concentrations between snow and aerosol show that snow chemistry basically reflects changes in the chemistry of the atmosphere. This gives us confidence in the reconstruction of past atmospheric change using some snow data. There are no significant correlations between aerosol and snow samples for ammonium and nitrate. This suggests that post-depositional and/or post-collection processes may alter ammonium and nitrate concentrations in snow. The fact that the measured cations in aerosol and snow always exceed the measured anions suggests that the atmosphere is alkaline over Glacier 1, Tien Shan. In aerosol and snow samples, calcium is the dominant cationic species, with sulfate and presumed carbonate being the dominant anions. There is a very good inverse relationship (r = 0.96) between the equivalence ratio of calcium to sulfate and the ratio of ammonium to sulfate in aerosols, but this relationship does not hold for snow. This further suggests that post depositional and/or post collection processes exert important controls on ammonium concentrations in snow. Although melt-freeze cycles might increase the concentration of all crustal species through progressive dissolution of dust, these cycles seem most important for magnesium and carbonate

Chemical Composition of Fresh Snow on Xixabangma Peak, Central Himalaya, During the Summer Monsoon Season

The physical and chemical analysis of ice cores recovered from glaciers in the Himalaya provide some of the best records of past climate change in the region (e.g. Qin and others, 2000; Thompson and others, 2000; Kang and others, 2001, 2002). In order to better understand the climatic and environmental records preserved in snow and ice, studies have investigated the precipitation chemistry in the high Himalaya, notably that the northern slopes of the central Himalaya (Mayewski and others, 1986; Jenkins and others 1987) and the southern slopes of the central Himalaya (Shrestha and others, 1997; Marinoni and others, 2001)

The Weddell Sea Region: An Important Precipitation Channel to the Interior of the Antarctic Ice Sheet as Revealed by Glaciochemical Investigation of Surface Snow Along the Longest Trans-Antarctic Route

Glaciochemical analysis of surface snow samples, collected along a profile crossing the Antarctic ice sheet from the Larsen Ice Shelf, Antarctic Peninsula, via the Antarctic Plateau through South Pole, Vostok and Komsomolskaya to Mirny station (at the east margin of East Antarctica), shows that the Weddell Sea region is an important channel for air masses to the high plateau of the Antarctic ice sheet (\u3e2000 m a.s.l.). This opinion is supported by the following. (1) The fluxes of sea-salt ions such as Na+, Mg2+ and Cl− display a decreasing trend from the west to the east of interior Antarctica. In general, as sea-salt aerosols are injected into the atmosphere over the Antarctic ice sheet from the Weddell Sea, large aerosols tend to decrease. For the inland plateau, few large particles of sea-salt aerosol reach the area, and the sea-salt concentration levels are low. (2) The high altitude of the East Antarctic plateau, as well as the polar cold high-pressure system, obstruct the intrusive air masses mainly from the South Indian Ocean sector. (3) For the coastal regions of the East Antarctic ice sheet, the elevation rises to 2000 m over a distance from several to several tens of km. High concentrations of sea salt exist in snow in East Antarctica but are limited to a narrow coastal zone. (4) Fluxes of calcium and non-sea-salt sulfate in snow from the interior plateau do not display an eastward-decreasing trend. Since calcium is mainly derived from crustal sources, and nssSO42− is a secondary aerosol, this again confirms that the eastward-declining tendency of sea-salt ions indicates the transfer direction of precipitation vapor

Stable-Isotopic Composition of Precipitation Over the Northern Slope of the Central Himalaya

Stable-water-isotope data (deltaD and delta(18)O) from three groups of samples (fresh-snow and snow-pit samples collected on Qomolangma (Mount Everest) and Xixabangma during field seasons 1997,1998 and 2001, and precipitation samples collected at Tingri station during summer 2000) are presented and used to survey the isotopic composition of precipitation over the northern slope of the central Himalaya. Multi-year snow-pit samples on Qomolangma have a local meteoric water-line (slope = 8) close to the global value. Deuterium excess (d = deltaD - 8delta(18)O) values at Tingri are much lower than those in fresh snow from Qomolangma, probably due to differences in moisture source and air-mass trajectories as well as local weather conditions. There is no obvious seasonal trend for d values in the Qomolangma region. A negative relationship exists between delta(18)O and d values in both fresh snow on Qomolangma and precipitation at Tingri. Fresh-snow samples collected from different altitudes on Xixabangma allow us to investigate the altitude effect on delta(18)O values in snow. Of four storm events, only one has an obvious altitude effect on delta(18)O variation and a very low gradient of -0.1% per 100 in elevation

Monsoon and Dust Signals Recorded in Dasuopu Glacier, Tibetan Plateau

During summer 1997, a 15m firn core was recovered from Dasuopu glacier (28°23\u27N, 85° 44\u27 E; 7000 m a.s.l.) on the northwest margin of Xixabangma Feng in the central Himalaya. Oxygen isotope values and concentrations of Ca2+, Mg2+, NH4+, SO42- and NO3- were measured over the 10 years of snow accumulation captured in the firn core. The seasonal variations of δ18O values and major-ion concentrations in the Dasuopu core indicated that summer monsoon and dust signals are clearly recorded in Dasuopu glacier. Annual variations in the δ18O values are controlled by the amount effect, with more negative (i.e. lighter) δ18O values representing summer monsoon precipitation characteristic of tropical regions. Higher concentrations of Ca2+, Mg2+ and SO42- reflect the influx of mineral aerosols from the vast arid and semi-arid desert regions to the north and west during the spring dust-storm period. High spring concentrations of NH4+ and NO3- appear to reflect changes in regional biogenic-source strength